Fourth Quarter 2006
INL Quarterly Site Environmental Report
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WATER SAMPLING

The ESER program samples precipitation, surface water and drinking water.  Monthly composite precipitation samples are collected from Idaho Falls and the Central Facilities Area (CFA) on the INL Site.  Weekly precipitation samples are collected from the Experimental Field Station (EFS) on the INL Site.  Surface and/or drinking water are sampled twice each year at 19 locations around the INL Site.  This occurs during the second and fourth quarters. 

Precipitation Sampling

Precipitation samples are gathered when sufficient precipitation occurs to allow for the collection of the minimum sample volume of approximately 20 mL.  Samples are taken of monthly composites from Idaho Falls and CFA, and weekly from the EFS.  Precipitation samples are analyzed for tritium.  Storm events in the fourth quarter of 2006 produced sufficient precipitation to yield 12 samples –three from CFA and Idaho Falls and six weekly samples from the EFS.

Tritium was measured above the 3s value in three of the 12 samples collected during the fourth quarter of 2006.  Low levels of tritium exist in the environment at all times as a result of cosmic ray reactions with water molecules in the upper atmosphere.  The EPA’s RadNet program collects precipitation samples from across the United States.  From 1980 to 2005, tritium measured in samples from Region 10 (which includes Idaho) ranged from -200 to 7500 pCi/L (EPA 2006).  Tritium measured in all second quarter ESER samples were within this range and were consistent with historical measurements at the INL Site, with a maximum of 124.0 ± 30.3 pCi/L at CFA.  Data for all fourth quarter 2006 precipitation samples collected by the ESER Program are listed in Table C-6 (Appendix C).

Drinking Water

Fourteen drinking water samples and one duplicate were collected from selected taps throughout southeast Idaho (Figure 11).  Samples were analyzed for gross alpha, gross beta, and tritium (3H).


Figure 11.                Drinking and surface water sampling locations.
 

Two of the samples exceeded the 3s value for gross alpha. It is not unusual to detect this constituent in water of the Snake River Plain, related to natural production from the basalts that make up the aquifer.  The maximum detectable result, a sample from Atomic City, had a gross alpha concentration of 1.81 ± 0.38 pCi/L.  This value is below the EPA and DOE limits for gross alpha in drinking water of 15 pCi/L and 30 pCi/L, respectively

Of the fifteen drinking water samples (including the duplicate) collected, all samples but one exceeded their 3s value for gross beta (Table 2).  The EPA Safe Drinking Water Act (SDWA) limits gross beta in drinking water based on an annual exposure of 4 mrem/yr.  Since data are reported from the laboratory as a concentration (i.e., pCi/L) a screening concentration of 50 pCi/L is used to meet this level (Appendix B-1).  The maximum concentration of gross beta detected was from Fort Hall and was lower than the SDWA screening value. Levels of gross beta observed in drinking water are not unusual given the basaltic terrain (USGS 2003).  All values are similar to those recorded in previous years, and are well below the levels outlined for drinking water protection (Appendix B-1).  All drinking water sample results may be found in Appendix C, Table C‑7.

Tritium was detected in two of the samples collected.  Detectable tritium concentrations were 92 ± 24 pCi/L at Mud Lake and 93 ± 29 pCi/L at Shoshone.  Both values are well below the EPA limit of 20,000 pCi/L and the DOE DCG of 2.0 x 106 pCi/L. Tritium values were within historical data collected by the ESER and within EPA measurements made through the RadNet program in Region 10 (Alaska, Idaho, Oregon, and Washington), which ranged from -87 ± 37 pCi/L to 1402 ± 63 pCi/L in the period 2000-2005.


 

Table 2.  Drinking water results greater than (>) 3s.

 

Sample Resultsa

Limits for Comparisona

Location

Result ± 1s

SDWAb

DOE DCGc

Gross Alpha

Atomic City

1.81 ± 0.38

15

30

Howe

1.03 ± 0.33

15

30

Gross Beta

Aberdeen

5.43 ± 0.57

50

100

Arco

1.51 ± 0.48

50

100

Atomic City

3.93 ± 0.52

50

100

Carey

2.65 ± 0.54

50

100

Fort Hall

7.89 ± 0.63

50

100

Howe

1.90 ± 0.48

50

100

Idaho Falls

3.16 ± 0.52

50

100

Minidoka

5.31 ± 0.59

50

100

Monteview

4.36 ± 0.53

50

100

Moreland

6.33 ± 0.55

50

100

Mud Lake

5.46 ± 0.59

50

100

Roberts

3.72 ± 0.53

50

100

Shoshone

4.70 ± 0.55

50

100

Taber

4.31 ± 0.52

50

100

Tritium

Mud Lake

92.0 ± 29.4

20,000

2 x 106

Shoshone

92.6 ± 29.4

20,000

2 x 106

a.       All values shown are in picocuries per liter (pCi/L).

b.       SDWA = Safe Drinking Water Act.

c.    DCG – Derived Concentration Guide.

Surface Water

Five surface water samples and one duplicate sample were collected from locations throughout southeast Idaho and were analyzed for tritium, gross alpha, and gross beta.  One of samples had measurable gross alpha activity greater than 3s and two of the samples had measurable tritium activity.  All six surface water samples were greater than their associated 3s values for gross beta activity (Table 3).  All reported levels of these constituents were much lower than the SDWA and the DCG values (Table B-1).

Table 3.                    Surface water results greater than (>) 3s.

 

 

Limits for Comparisona

Location

Result ± 1s

SDWA

DOE DCG

Gross Alpha

Hagerman

1.18 ± 0.34

15

30

Gross Beta

Bliss

5.24 ± 0.55

50

100

Buhl

4.15 ± 0.53

50

100

Buhl (duplicate)

5.24 ± 0.57

50

100

Hagerman

4.34 ± 0.52

50

100

Idaho Falls

2.55 ± 0.46

50

100

Twin Falls

7.71 ± 0.57

50

100

Tritium

Buhl (duplicate)

90.1 ± 29.6

20,000

2 x 106

Hagerman

92.5 ± 29.7

20,000

2 x 106

a.    All values shown are in picocuries per liter (pCi/L).

 

The presence of gross alpha and gross beta in surface water (particularly the springs) is typically related to dissolution of naturally occurring radionuclides (i.e., uranium, radium, potassium) by groundwater as it flows through the surrounding basalts (Twinning and Rattray 2003).  Levels of gross alpha and gross beta in all samples are similar to results from recent years.  All gross alpha and gross beta results can be found in Appendix C, Table C-7.

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