Precipitation Sampling

When adequate precipitation occurred, samples were taken on a monthly interval from Idaho Falls and CFA, and on a weekly interval from the EFS.  A minimum sample volume of 20 mL of precipitation is needed for a single sample.  Precipitation samples are analyzed for tritium.  For the second quarter of 2001, there was enough precipitation for a total of six samples – two monthly composites from Idaho Falls, two monthly composites from CFA, and two weekly samples from EFS. 

Of the precipitation samples collected, two EFS samples (collected on April 4 and April 18) yielded tritium results greater than the 2s uncertainty.  The sample collected on April 4 did not exceed the MDC, while the sample collected on April 18 did exceed the MDC (see table B-1 for MDC values).  Tritium was also detected above the 2s level in the Idaho Falls sample in May and the duplicate sample from Idaho Falls in June.  However, neither of these samples exceeded their associated MDC, indicating false positives. 

While there are no specific limits on the amount of tritium in precipitation, the SDWA limits tritium in drinking water to 2 x 104 pCi/L (Appendix B-1).  The level of tritium detected in the sample from EFS that was above its associated 2s and MDC value was 140 times lower than the SDWA limit.

Although tritium was detected (above its associated 2s and MDC) in precipitation from EFS and an INEEL source cannot be completely discounted for contributing to this, the measured level was within the range of background tritium that exists throughout the world.  Low levels of tritium exist in the environment at all times.  The major natural source of tritium is cosmic ray reactions in the upper atmosphere.  From 1978 to 2001 the EPA, as part of its ERAMS, measured tritium from –2.00 x 102 to 7.38 x 106 pCi/L in precipitation samples across the United States (EPA, 2002).  Data for all precipitation samples collected by the ESER Program during the second quarter of 2001, are listed in Table C-6 (Appendix C).

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