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2005 INL Annual Site Environmental Report
Appendix C - U.S. Geological Survey 2005 INL Publication Abstracts

LeRoy L. Knobel - United States Geological Survey

Water Resources Data, Idaho, 2005: Volume 1. Surface Water Records (T.S. Brennan, A.K. Lehmann, and O’Dell, I.)

Water resources data for the 2005 water year for Idaho consists of records of stage, discharge, and water quality of streams; stage, contents, and water quality of lakes and reservoirs; discharge of irrigation diversions; and water levels and water quality of groundwater. The two volumes of this report contain discharge records for 204 stream-gaging stations and 9 irrigation diversions; stage only records for 5 stream-gaging stations; stage only for 6 lakes and reservoirs; contents only for 13 lakes and reservoirs; water-quality for 26 stream-gaging stations and partial record sites, 19 lakes sites, and 450 groundwater wells; and water levels for 465 observation network wells. Additional water data were collected at various sites not involved in the systematic data collection program and are published as miscellaneous measurements.

Water Resources Data, Idaho, 2005: Volume 2. Ground Water Records (A.M. Campbell, S.N. Conti, I. O’Dell)

Water resources data for the 2005 water year for Idaho consists of records of stage, discharge, and water quality of streams; stage, contents, and water quality of lakes and reservoirs; discharge of irrigation diversions; and water levels and water quality of groundwater. The two volumes of this report contain discharge records for 204 stream-gaging stations and 9 irrigation diversions; stage only records for 5 stream-gaging stations; stage only for 6 lakes and reservoirs; contents only for 13 lakes and reservoirs; water-quality for 26 stream-gaging stations and partial record sites, 19 lakes sites, and 450 groundwater wells; and water levels for 465 observation network wells. Additional water data were collected at various sites not involved in the systematic data collection program and are published as miscellaneous measurements.

Petrogenesis of an evolved olivine tholeiite and chemical stratigraphy of cores USGS 127, 128, and 129, Idaho National Engineering and Environmental Laboratory (Claire Grimm Chadwick)

The eastern Snake River Plain (ESRP) volcanic province has been dominated by basaltic volcanism for at least 3.2 Ma. Basalt core from three boreholes , USGS 127, 128, and 129, drilled at the Idaho National Engineering and Environmental Laboratory (INEEL) are used to document the subsurface chemostratigraphy of ESRP basalts and to understand the origin of their chemical variability. The stratigraphy of these coreholes was defined by detailed geochemical analysis of individual lava flows combined with paleomagnetic inclination data. Lava flows with similar chemistry and paleomagnetic inclination were identified and correlated between the three cores to refine the subsurface stratigraphy in this region.

One lava flow group from these cores, known as the “high K” flow group, is distinguished from typical olivine tholeiites on the ESRP by unusually high concentrations of incompatible elements and unusually low Sr isotopic ratios. The major element, trace element, and isotopic characteristics of this flow group were studied in detail in order to explain its petrogenetic history. Mass-balance modeling indicates that fractionation of plagioclase, olivine, magnetite, and apitite from a plausible olivine tholeiite parent magma could produce the high K flow group lavas. However, thermodynamic modeling of fractionation of the parent magma under higher redox conditions could not reproduce the required mineral assembledge. Another mechanism for the removal of magnetite and apitite in addition to olivine and plagioclase from the high K flow group parent magma is required. The high K flow group may be part of a chemically continuous series of lavas that includes the underlying lava flow group, designated here as flow group 4.

Historical Development of the U.S. Geological Survey Hydrologic Monitoring and Investigative Programs at the Idaho National Engineering and Environmental Laboratory, Idaho, 1949 to 2001 (LeRoy L. Knobel, Roy C. Bartholomay, and Joseph P. Rousseau)

This report is a summary of the historical development, from 1949 to 2001, of the U.S. Geological Survey’s (USGS) hydrologic monitoring and investigative programs at the Idaho National Engineering and Environmental Laboratory. The report covers the USGS’s water-level monitoring program, water-quality sampling program, geophysical program, geologic framework program, drilling program, modeling program, surface-water program, and unsaturated-zone program. The report provides physical information about the wells, and information about the frequencies of sampling and measurement. Summaries of USGS published reports with U.S. Department of Energy (DOE) report numbers also are provided in an appendix. This report was prepared by the USGS in cooperation with the DOE.

Genetic controls on basalt alteration within the eastern Snake River Plain aquifer system, Idaho (John Mazurek)

This study examines the origin of basalt alteration that correlates with the sharp, but irregular boundary between active and deeper, much less conductive portions of the eastern Snake River Plain (ESRP) aquifer system. I specifically investigate three hypotheses for the origin of the boundary: (1) that basalt alteration took place in-situ, post-emplacement, while the basalt was within the ESRP aquifer system under ambient aquifer temperature and aqueous geochemical conditions, (2) that basalt alteration took place in-situ, post-emplacement, while the basalt was within the ESRP aquifer system under elevated temperature and different aqueous geochemical conditions, and (3) that basalt altered syn-emplacement, during the peperitization process.

A majority of altered basaltic units in borehole Middle 1823 also exhibit prominent syn-emplacement, peperitic intermingling between the molten basalt and wet sediment. Peperitization of basalts is distinguished from subaerially or palagonitized basalt by zones of intermingled basalt and sediment displaying amoeboid-shaped basalt clasts with fluidal, oxidized margins intermingling with sediment at glass-rich contact regions between basalt and sediment, as well as clastic dikes of sediment and sediment amygdules within basalt flows. Thus some alteration occurred during the peperitization of the basalt, which was later overprinted by in-situ alteration.

Fluid inclusion microthermometry indicates that in-situ alteration-associated calcite precipitated at temperatures 7-20 oC higher than the present day temperatures. This is substantially higher than expected ambient variability within the aquifer and supports hypothesis # 2. Transient inputs of warm, reactive hydrothermal groundwater from depth (McLing et al., 1997; McLing et al., 2002; Morse and McCurry, 2002; Morse, 2002) with local variations in extent, magnitude, and flux, best explain the 3 dimensional variations in the morphology of the contact between the active portion and the base of the ESRP aquifer.

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Laboratory to the Hagerman Area, Idaho, 2003 (Gordon W. Rattray, Amy J. Wehnke, L. Flint Hall, and Linford J. Campbell)

The U.S. Geological Survey and the Idaho Department of Water Resources, in cooperation with the U.S. Department of Energy, sampled water from 14 sites as part of an ongoing study to monitor the water quality of the eastern Snake River Plain aquifer between the southern boundary of the Idaho National Laboratory (INL) and the Burley-Twin Falls-Hagerman area. The State of Idaho, Department of Environmental Quality, Division of INL Oversight and Radiation Control cosampled with the U.S. Geological Survey and the Idaho Department of Water Resources and their analytical results are included in this report. The samples were collected from four domestic wells, two dairy wells, two springs, four irrigation wells, one observation well, and one stock well and analyzed for selected radiochemical and chemical constituents. Two quality-assurance samples, sequential replicates, also were collected and analyzed.

None of the concentrations of radiochemical or organic-chemical constituents exceeded the maximum contaminant levels for drinking water established by the U.S. Environmental Protection Agency. However, the concentration of one inorganic-chemical constituent, nitrate (as nitrogen), in water from site MV-43 was 20 milligrams per liter which exceeded the maximum contaminant level for that constituent. Of the radiochemical and chemical concentrations analyzed for in the replicate-sample pairs, 267 of the 270 pairs (with 95 percent confidence) were statistically equivalent.

Review of the Transport of Selected Radionuclides in the Interim Risk Assessment for the Radioactive Waste Management Complex, Waste Area Group 7 Operable Unit 7-13/14, Idaho National Engineering and Environmental Laboratory, Idaho (Joseph P. Rousseau, Edward R. Landa, John R. Nimmo, L. DeWayne Cecil, LeRoy L. Knobel, Pierre D. Glynn, Edward M. Kwicklis, Gary P. Curtis, Kenneth G. Stollenwerk, Steven R. Anderson, Roy C. Bartholomay, Clifford R. Bossong, and Brennon R. Orr)

The U.S. Department of Energy (DOE) requested that the U.S. Geological Survey conduct an independent technical review of the Interim Risk Assessment (IRA) and Contaminant Screening for the Waste Area Group 7 (WAG-7) Remedial Investigation, the draft Addendum to the Work Plan for Operable Unit 7-13/14 WAG-7 comprehensive Remedial Investigation and Feasibility Study (RI/FS), and supporting documents that were prepared by Lockheed Martin Idaho Technologies, Inc.

The purpose of the technical review was to assess the data and geotechnical approaches that were used to estimate future risks associated with the release of the actinides americium, uranium, neptunium, and plutonium to the Snake River Plain aquifer from wastes buried in pits and trenches at the Subsurface Disposal Area (SDA). The SDA is located at the Radioactive Waste Management Complex in southeastern Idaho within the boundaries of the Idaho National Engineering and Environmental Laboratory. Radionuclides have been buried in pits and trenches at the SDA since 1957 and 1952, respectively. Burial of transuranic wastes was discontinued in 1982.

The five specific tasks associated with this review were defined in a “Proposed Scope of Work” prepared by the DOE, and a follow-up workshop held in June 1988. The specific tasks were (1) to review the radionuclide sampling data to determine how reliable and significant are the reported radionuclide detections and how reliable is the ongoing sampling program, (2) to assess the physical and chemical processes that logically can be invoked to explain true detections, (3) to determine if distribution coefficients that were used in the IRA are reliable and if they have been applied properly, (4) to determine if the transport model predictions are technically sound, and (5) to identify issues needing resolution to determine technical adequacy of the risk assessment analysis, and what additional work is required to resolve those issues.

Development of Property-Transfer Models for Estimating the Hydraulic Properties of Deep Sediments at the Idaho National Engineering and Environmental Laboratory, Idaho (Kari A. Winfield)

Because characterizing the unsaturated hydraulic properties of sediments over large areas or depths is costly and time consuming, development of models that predict these properties from more easily measured bulk-physical properties is desirable. At the Idaho National Engineering and Environmental Laboratory, the unsaturated zone is composed of thick basalt flow sequences interbedded with thinner sedimentary layers. Determining the unsaturated hydraulic properties of sedimentary layers is one step in understanding water flow and solute transport processes through this complex unsaturated system. Multiple linear regression was used to construct simple property-transfer models for estimating the water-retention curve and saturated hydraulic conductivity of deep sediments at the Idaho National Engineering and Environmental Laboratory. The regression models were developed from 109 core sample subsets with laboratory measurements of hydraulic and bulk-physical properties. The core samples were collected at depths of 9 to 175 meters at two facilities within the southwestern portion of the Idaho National Engineering and Environmental Laboratory¿the Radioactive Waste Management Complex, and the Vadose Zone Research Park southwest of the Idaho Nuclear Technology and Engineering Center. Four regression models were developed using bulk-physical property measurements (bulk density, particle density, and particle size) as the potential explanatory variables. Three representations of the particle-size distribution were compared: (1) textural-class percentages (gravel, sand, silt, and clay), (2) geometric statistics (mean and standard deviation), and (3) graphical statistics (median and uniformity coefficient). The four response variables, estimated from linear combinations of the bulk-physical properties, included saturated hydraulic conductivity and three parameters that define the water-retention curve.

For each core sample,values of each water-retention parameter were estimated from the appropriate regression equation and used to calculate an estimated water-retention curve. The degree to which the estimated curve approximated the measured curve was quantified using a goodness-of-fit indicator, the root-mean-square error. Comparison of the root-mean-square-error distributions for each alternative particle-size model showed that the estimated water-retention curves were insensitive to the way the particle-size distribution was represented. Bulk density, the median particle diameter, and the uniformity coefficient were chosen as input parameters for the final models. The property-transfer models developed in this study allow easy determination of hydraulic properties without need for their direct measurement. Additionally, the models provide the basis for development of theoretical models that rely on physical relationships between the pore-size distribution and the bulk-physical properties of the media. With this adaptation, the property-transfer models should have greater application throughout the Idaho National Engineering and Environmental Laboratory and other geographic locations.

References

Brennan, T.S., Lehmann, A.K., and O’Dell, I., 2005, Water Resources Data, Idaho, 2005: Volume 1. Surface Water Records: U.S. Geological Survey Water-Data Report ID-05-1, 469 p.

Campbell, A.M., Conti, S.N., and O’Dell, I., 2005, Water Resources Data, Idaho, 2005: Volume 2. Ground Water Records: U.S. Geological Survey Water-Data Report ID-05-2, 354 p.

Chadwick, C.G., 2005, Petrogenesis of an evolved olivine tholeiite and chemical stratigraphy of cores USGS 127, 128, and 129, Idaho National Engineering and Environmental Laboratory: Idaho State University, Department of Geosciences Master of Science Thesis, 133 p.

Knobel, L.L., Bartholomay, R.C., and Rousseau, J.P., 2005, Historical development of the U.S. Geological Survey hydrologic monitoring and investigative programs at the Idaho National Engineering and Environmental Laboratory, Idaho, 1949 to 2001: U.S. Geological Survey Open-File Report 2005-1223 (DOE/ID-22195), 93 p.

Mazurek, John, 2005, Genetic controls on basalt alteration within the eastern Snake River Plain aquifer system, Idaho: Idaho State University, Department of Geosciences Master of Science Thesis, 212 p.

Rattray, G.W., Wehnke, A.J., Hall, L.F., and Campbel, L.J., 2005, Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Laboratory to the Hagerman Area, Idaho, 2003: U.S. Geological Survey Open-File Report 2005-1125 (DOE/ID-22193), 25 p.

Rousseau, J.P., Landa, E.R., Nimmo, J.R., Cecil, L.D., Knobel, L.L., Glynn, P.D., Kwicklis, E.M, Curtis, G.P., Stollenwerk, K.G., Anderson, S.R., Bartholomay, R.C., Bossong, C.R., and Orr, B.R., 2005, Review of the transport of selected radionuclides in the Interim Risk Assessment for the Radioactive Waste Management Complex, Waste Area Group 7 Operable Unit 7-13/14, Idaho National Engineering and Environmental Laboratory, Idaho: U.S. Geological Survey Scientific Investigations Report 2005-5026 (DOE/ID-22192), Volume I, Volume II, Appendix, [variously paged].

Winfield, K.A., 2005, Development of Property-Transfer Models for Estimating the Hydraulic Properties of Deep Sediments at the Idaho National Engineering and Environmental Laboratory, Idaho: U.S. Geological Survey Scientific Investigations Report 2005-5114 (DOE/ID-22196), 49 p.

 

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